@article{oai:osu.repo.nii.ac.jp:00000470, author = {谷口, 省吾 and タニグチ, ショウゴ and TANIGUCHI, Shogo}, journal = {大阪産業大学人間環境論集}, month = {Mar}, note = {P(論文), 本研究では,大阪府の寝屋川を対象にPFCとPPCPの測定を行った。PFCの中のPFOSはPOPsに追加された化合物で,今後廃絶される物質である。測定は,PFCsで16種類,PPCPで17種類の測定を行った。測定は,SPEとLCMSMSを用いる測定法によって行った。結果は,PFCsでカルボン酸類ではPFOAが最も高い濃度で含まれており,そのほかではPFHpAやPFHxAなどが多く含まれていた。スルホン酸類では,PFOSがほとんどを占めており,その他の化合物は少なかった。医薬品類については,高脂血症剤のCAと抗生物質のCAM, LVFXが多く含まれていた。また,医薬品類の用途でまとめた場合100ng/Lの高い濃度で検出されており,河川水中の医薬品類の評価を行う場合,用途ごとに分けて評価を行う必要があることを示唆した。, PPCPs and PFCs are widely detected in a large number of water bodies these days, which is a matter of concern among people. PFOS was recently added to POPs category, and its limited production and uses can be expected in future. Presence of PPCPs and PFCs in the Neya River, Osaka, Japan was investigated in this study.Samples from the river (six representative sampling points, November 2008) were pretreated (SPE) and analyzed using LCMS/MS. Total sixteen PFCs were detected in the samples. PFOA exhibited the largest concentrations among the detected carboxylic acids in addition to significantly larger concentrations of PFHpA and PFHxA. Similarly PFOS showed the largest concentrations among the detected sulfonic acids. Total seventeen PPCPs belonging to three categories (antihyperlipoproteinemic,antiinflammatory, antipyretic and antibiotic) were detected in the samples, where Clofibric acid, Clarithromycin and LVFX exhibited relatively larger concentrations.Though concentrations of individual PPCPs detected in this study were small, total concentrations of those belonging to a particular category exceeded 100ng/L. Therefore, total concentration of PPCPs belonging to a category rather than their individual concentrations may better describe their occurrence in natural water bodies like rivers.}, pages = {193--199}, title = {寝屋川流域における医薬品類および有機フッ素化合物の存在実態}, volume = {9}, year = {2010} }